I never had any problems with brakes. I overhauled calipers (piston seals), master cylinder, new vacuum hose to booster as a matter of course, new rear cylinders (a matter of time as they are still good to overhaul). I had flushed out hard lines with propanol and compressed air (lots of compressed air to make sure there was nothing left in lines.) Shoes and pads were like new. Cleaned mechanical bits in rear drums and lubed touching moving parts with brake grease. Replaced new rubber hoses with braided to see the difference (didn't notice much if any). Never had any problems bleeding brakes or their operations. The point is it dshould work if everything was done correctly. I think once the problem is found it will be something simple and overlooked. (Isn't it always).
I'm not much good at diagnosing from afar as I use my sense of hearing, touch and eyes when diagnosing the problem something you can't do from a computer screen. It's the same way when I fix computers. It's just me. But two heads there would definitely be an asset. Sometimes you get so involved in a problem you can't see the forrest for the trees.
Hard pedal, engine off. To the floor when engine on, would indicate the booster is working but that extra pressure on the brake fluid is causing it to expand to somewhere it can't get to with less unboosted pressure. Binding caliper pistons? Binding rear cylinder pistons? Expanding rubber hoses if they're not braided? (I got caught with the expanding new rubber/plastic clutch hose thing). Did you use brand name master cylinder seal kit? (I used TRW from British Parts Northwest.) Brand X may be less precisely made? Seals put on right way? (They usually only meant to go on one way so expanding pressure opens them up to create a tighter seal with pressure.)
TR7 Spider - 1978 Spitfire - 1976 Spitfire - 1988 Tercel 4X4 - Kali on Integra - 1991 Integra - Yellow TCT